The Centers for Disease Control (CDC) cites PPD as a contact allergen, and should not be directly applied to the skin. When used in hair dyes, it may cause mild contact dermatitis on the forehead, eyelids or ears — wherever it comes in contact with the skin. Reactions usually only occur while the dye is oxidizing, versus once it has already oxidized, as is the case with dyed fabrics and furs. People who regularly work with PPD can develop allergies to it, and must take certain precautions to avoid coming in contact with it. Although the most common absorption of PPD into the body is through the skin, it can cause allergic reactions when it is inhaled, or absorbed by the eyes or ingested.
One of the most dangerous applications of PPD is when it is added to henna, a natural dye. When used for temporary tattoos, henna laced with PPD is known as “Black Henna.” Although this is not an approved use for PPD in the United States, some tattoo artists will illegally add the chemical to henna for darker temporary tattoos that dry faster than pure henna tattoos. Because the dye is applied while the PPD is in its oxidation process, its potential as an allergen is increased. Black Henna tattoos often result in a skin reaction similar to a chemical burn, which in turn results in a scar where the skin was tattooed.
When added to henna, the concentration of PPD is often much higher than what is approved for use in hair dyes, resulting in a minor to major allergic reaction. Once a person who has been exposed to PPD has an allergic reaction, they may suffer a lifelong sensitivity to the chemical.
-- 24 May 2010, 18:51 --
What is PPD and what is its connection to henna?
PPD is the main allergen identified in allergic reactions to decorative skin paintings.
Para-phenylenediamine is a colourless/slightly pink, grey or yellow crystalline solid (lumps or powder). On oxidation, usually through exposure to air, it turns red, brown then finally black. PPD is essentially a dye and chemical intermediate.
It may also been found in textile or fur dyes, dark coloured cosmetics, temporary tattoos, photographic developer and lithography plates, photocopying and printing inks, black rubber, oils, greases and gasoline.
PPD is a low toxicity diamine used as a component of engineering polymers and composites, aramid fibers, hair dyes, rubber chemicals, textile dyes and pigments. PPD is selected for the outstanding properties it imparts, including high temperature stability, high strength, and chemical and electrical resistance.18
Some particularly atrocious misinformation twists have led to PPD being described as a black mineral from the banks of the River Nile. This gives PPD an undeserved distinction as being both natural and exotic. Obviously, anyone who proposes this myth, knowing its falseness, is not only lying, but purposefully harming people.
PPD gained infamy from being an ingredient, used either pure or as an “additive” to henna, to create or give henna a black tattoo-like appearance. This is due to the ‘fad’ quality of henna as a temporary tattoo. Traditional artists and traditionally trained artists are aware that the words “henna” and “black” do not go together:
“Henna gives an orange/reddish-brown stain. Any product that calls itself black henna must contain an ingredient in addition to pure henna to achieve its ebony color. In most cases, this added ingredient is PPD, that is also found in many black hair dyes. Another reason for using PPD additives is to speed up the tattooing process. While traditional henna staining takes 2-12 hours, a pure black tattoo can be achieved within an hour or two with the addition of PPD, and there will be a longer lasting effect as well.
The findings of a mass spectrometry analysis of commercial black henna performed by Chung et al. demonstrated a major peak at the mass-charge ratio of 108.1, which corresponds exactly to the molecular weight of PPD. There was no line at the molecular weight 174.2, that of the active agent of pure henna. This was the first sophisticated, scientific proof of what almost every tattoo artist or supplier had known for years.”
In other words, there is no such plant as or plant that gives “black henna” and here we see scientific proof that it is the chemical called PPD that makes this phenomenon. It’s nothing to do with henna at all, other than a piggyback ride from a legitimate and healthy art form turned into a marketable and highly profitable scheme that harms people. Luckily, there are people speaking out on this to make the people who manufacture, sell and use PPD to be held liable for what they are doing.
An important factor to remember about PPD is that it is cheap. You can buy very cheap black hair dye and mix it with henna (or use it pure if you are that much of a @#$%!) and make lots of money. However, caveat emptor to anyone reading this with ulterior motives- I can guarantee you won’t make enough to cover your butt when you are sued.
-- 24 May 2010, 18:51 --
Alternative names for para-phenylenediamine:
PPD or PPDA, Phenylenediamine base, p-Phenylenediamine, 4-Phenylenediamine, 1,4-Phenylenediamine, 4-Benzenediamine, 1,4-Benzenediamine, para-Diaminobenzene (p-Diaminobenzene), para-Aminoaniline (p-Aminoaniline), Orsin™, Rodol™, Ursol™, 2 - Nitro - 1,4 - diaminobenzene, Dye GS, Durafur Brown 2R, Fouramine 2R, 1,4 - Diaminonitrobenzol (German), 1,4 - Diamino - 2 - nitrobenzene, C.I. Oxidation Base 22, Fourrine Brown 2R, NCI - C02222, 4 - Amino - 2 - nitroaniline, 2 - Nitro - 1,4 - benzenediamine, Fourrine 36, o - Nitro - p - phenylenediamine, 2 - Nitro - 1,4 - phenylenediamine, Nitro - p - phenylenediamine, 2 - Nitro - p - phenylenediamine, Oxidation Base 22, Ursol Brown RR, C.I. 76070, Zoba Brown RR, 2 - Nitro - 4 - aminoaniline,
Chemical information:
Formula:4-Phenylenediamine base - C6H8N2
Cass number: 106-50-3
Cross reactions: Azo and aniline dyes, Benzocaine, Procaine, Para-aminobenzoic acid (PABA), Para-aminosalicylic acid, Sulfonamides, Carbutamide, HydroDIURII
Appearance: White to slightly red solid crystals that darken on exposure to air.
Sensitizer: intermediate, partially oxidised PPD
Patch Test: 2% PPD in petrolatum